Rigorous Treatment of Metastable States in the van der Waals-Maxwell Theory
نویسندگان
چکیده
where f (p, 04-) is the Helmholz free energy density (HFED) in the limit ~, --~ 0; c~ = J" ~b(r)d~r; and fo(p) is the HFED for the case 'b = 0. It is shown rigorously that, for periodic boundary conditions, the conditional probability for a system in the grand canonical ensemble to violate the constraints at time t > 0, given that it satisfied them at time 0, is at most At, where 2~ is a quantity going to 0 in the limit
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تاریخ انتشار 2004